Chapter 1. Formally-kinetic description of one- and two-step reactions

from the book Viktor Korobov & Valery Ochkov "Chemical kinetic with Mathcad & Maple"

png - picture, MC11, MC13 и MC14-15 - Mathcad-files of different versions of Matcad for downloading

MCS - on-line Mathcad calculation

***- working

Fig. 1.1.

Analytical solution of the direct kinetic problem for the simple reaction by Mathcad

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MC11

MC13

MC14

 

Fig. 1.2.

The derivation of the kinetic equation of the first-order reaction

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MC11

MC13

MC14

 

Fig. 1.3.

Kinetic curves of the reagent in the elementary reactions of various orders

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MC11

MC13

MC14

 

Fig. 1.4.

Half-life times for the reactions of various orders

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MC11

MC13

MC14

 

Fig. 1.5.

Model kinetic curves for the reactions of various orders and their anamorphosises in linearize coordinates

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MC11

MC13

MC14

 

Fig. 1.6.

The solution of the direct kinetic problem for the second-order reaction in case of inequality of the reagents’ initial concentrations

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MC11

MC13

MC14

MCS

Fig. 1.7.

Solution of the direct problem for the first-order two-way reaction

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MC11

MC13

MC14

MCS

Fig. 1.8.

Solution of direct kinetic problem for second-order reversible reaction А+ВС+D

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MC11

MC13

MC14

MCS

Fig. 1.9.

Derivation of kinetic curve equation for intermediate product in successive first-order reaction with the help of dsolve function

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Maple 9

Fig. 1.10.

Kinetic curves of the participant of successive first-order reaction

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MC11

MC13

MC14

MCS

Fig. 1.11.

Trend of kinetic curves for intermediate and final product of the successive reactions with different ratio

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MC11

MC13

MC14

 

Fig. 1.12.

Derivation of kinetic equations for successive reactions in Maple

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Maple 9

Fig. 1.13.

Dialog box Interactive ODE Analyzer

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Fig. 1.14.

Solution of kinetic problem with the help of visually oriented elements of Maple system

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Fig. 1.15.

Kinetic curves of the participants of successive second-order reaction (on-line calculation

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MC11

MC13

MC14

MCS

Fig. 1.16.

Kinetic equations and corresponding kinetic curves for the participants of parallel first-order reaction

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MC11

MC13

MC14

MCS

Fig. 1.17.

For the derivation of kinetic equation for methyl halogenide hydrolysis process

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Maple 9

Fig. 1.18.

Solution of direct kinetic problem for self-catalyzed reaction

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MC11

MC13

MC14

MCS

 

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